Crystal structure and magnetic properties of a Cu4O4 cubane complex with N-(2-hydroxybenzyl)-propanolamine

被引：31
|
作者：
Xie, YS
Bu, WM
Xu, XL
Jiang, H
Liu, QL [1 ]
Xue, Y
Fan, YG
机构：
[1] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[3] Jilin Univ, State Key Lab Supramol Structr & Spect, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 10期
关键词：
crystal structures; copper(II) complexes; magnetic properties; hydrogen bonds;
D O I：
10.1016/S1387-7003(01)00278-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [Cu(L-1)](4)(1) (H2L1 = N-(2-hydroxybenzyl)-propanolamine) contains a Cu4O4 cubane core, involving four intramolecular hydrogen bonds. Magnetic studies reveal a good linear correlation between 2J and the bridge angle phi; the more antiferromagnetic trend than the literature correlations for the alkoxo-bridged complexes is ascribed to the additional superexchange pathways via the multiple hydrogen bonds. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码：558 / 560
页数：3
相关论文
共 50 条
  • [21] A chiral supramolecular architecture [Cu2(4,4′-bipyridine)2(sala)2]n • 4.5nH2O(sala=N-(2-hydroxybenzyl)-L-alanine anion)
    Lou, BY
    Yuan, DQ
    Gao, SY
    Xu, Y
    Han, L
    Hong, MC
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2004, 707 (1-3) : 231 - 234
  • [22] Tetranuclear Copper(II) Complexes Bearing Cu4O6 and Cu4O4 Cores: Synthesis, Structure, Magnetic Properties, and DFT Study
    Banerjee, Atanu
    Singh, Reena
    Mondal, Pallab
    Colacio, Enrique
    Rajak, Kajal Krishna
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (05) : 790 - 798
  • [23] Synthesis and crystal structure of poly{diaqua[N-(2-hydroxybenzyl)-D,L-aspartate]cadmium(II)}
    Lou, BY
    Yuan, DQ
    Han, L
    Wu, BL
    Hong, MC
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 759 - 762
  • [24] Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of the Copper（II） Complex [Cu4O4（phen）4（ClC6H4COO）2（H2O）2]·（H2O）3
    LI Weia② LI Chang-Hongb② YANG Ying-Quna KUANG Yun-Feia a (Department of Chemistry and Materials Science
    [J]. Chinese Journal of Structural Chemistry, 2006, (11) : 1331 - 1336
  • [25] Synthesis and Crystal Structure of Poly{diaqua[N-(2-hydroxybenzyl)- D,L- aspartate]cadmium(II)}
    LOU Ben-Yong YUAN Da-Qiang HAN Lei WU Ben-Lai HONG Mao-Chun (State Key Laboratory of Structural Chemistry
    [J]. Chinese Journal of Structural Chemistry, 2005, (07) : 759 - 762
  • [26] Synthesis and Crystal Structure of Poly{diaqua[N-(2-hydroxybenzyl)- D,L- aspartate]cadmium(II)}
    LOU BenYong YUAN DaQiang HAN Lei WU BenLai HONG MaoChun State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China
    [J]. 结构化学, 2005, (07) : 759 - 762+736
  • [27] Hydrothermal synthesis, crystal structure and electrochemical properties of the copper(II) complex [CU4O4(phen)4(ClC6H4COO)2(H2O)2].(H2O)3
    Li Wei
    Li Chang-Hong
    Yang Ying-Qun
    Kuang Yun-Fei
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (11) : 1331 - 1336
  • [28] Solution study and crystal structure of a pentacoordinate zinc(II) complex with N,N"bis-(2-hydroxybenzyl)diethylenetriamine
    Xie, YS
    Xue, Y
    Kou, FP
    Lin, RS
    Liu, QL
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2001, 53 (01) : 91 - 97
  • [29] Synthesis, Crystal Structure and PTPs Inhibition of a Zinc(Ⅱ) Complex with N-(4-hydroxybenzyl)-L-serine
    李艳红
    卢丽萍
    朱苗力
    袁彩霞
    冯思思
    高增强
    [J]. Chinese Journal of Structural Chemistry, 2017, 36 (02) : 316 - 323
  • [30] Tetracopper complexes with two-mode cubane-like Cu4O4 core from similar hydroxyl-rich salicylaldehyde Schiff bases: Structure and magnetic properties
    Yang, Bing
    Pan, Jiali
    Meng, Xianggao
    Cao, Jinge
    Li, Yuyi
    Xiao, Fengping
    Li, Dongfeng
    [J]. POLYHEDRON, 2016, 110 : 182 - 187
12345