We report n-channel enhancement-mode GaAs metal-insulator-semiconductor Field Effect Transistors (MISFETs) with similar to 6 nm equivalent oxide thickness of molecular-and-atomic (MAD) depositioned Si3N4 as the gate dielectric. The GaAs based MISFETs were fabricated using a gate-first process that preserved the channel inversion characteristic in MIS capacitor structures [W. P. Li, X. W. Wang, Y. X. Liu, and T. P. Ma, Appl. Phys. Lett. 90, 193503 (2007)]. The channel inversion characteristics of the GaAs MIS capacitors, measured by the quasistatic C-V (capacitor-voltage) technique, were well maintained throughout the entire fabrication process with temperatures up to 800 degrees C. C-V hysteresis as small as 100 mV was achieved. The Si3N4-gated GaAs MISFETs clearly demonstrated the enhancement-mode, gate-modulated I-d-V-d transfer characteristics with channel inversion. (C) 2008 American Institute of Physics.