Recent Advances in Aluminum Compounds for Catalysis

被引：36
|
作者：
Ni, Congjian [1 ]
Ma, Xiaoli [1 ]
Yang, Zhi [1 ]
Roesky, Herbert W. [2 ]
机构：
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Beijing 100081, Peoples R China
[2] Georg August Univ, Inst Inorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 2022卷 / 10期
关键词：
Aluminum; Copolymerization; Hydroamination; Hydroboration; Hydrosilylation; MAIN-GROUP ELEMENTS; CYCLIC CARBONATES; HIGHLY EFFICIENT; ELECTROPHILIC ACTIVATION; SELECTIVE HYDROBORATION; RUTHENIUM COMPLEX; SMALL MOLECULES; N-HETEROCYCLES; LEWIS-ACID; CO2;
D O I：
10.1002/ejic.202100929
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review highlights recent advances in the research of organoaluminum complexes in catalysis. Many fundamental transformations can be carried out by aluminum catalysts, such as hydroboration, hydroamination, copolymerization and CO2 insertion reactions, hydrosilylation, and hydroacetylenation of carbodiimides, which make use of the abundant reserves of aluminum in the earth's crust to accomplish the transformation. Recent research in the field has shown that these systems have extraordinary catalytic activity and are inexpensive, abundant, and environmentally friendly.
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页数：15
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