Recent Advances in Catalysis with Transition-Metal Pincer Compounds

被引:189
|
作者
Valdes, Hugo [1 ]
Garcia-Eleno, Marco A. [2 ]
Canseco-Gonzalez, Daniel [3 ,4 ]
Morales-Morales, David [1 ]
机构
[1] Univ Nacl Autonoma Mexico, Inst Qum, Circuito Exterior S-N,Ciudad Univ, Mexico City 04510, DF, Mexico
[2] Univ Nacl Autonoma Estado Mexico, Ctr Conjunto Invest Qum Sustentable UAEM UNAM, Carretera Toluca Atlacomulco Km 14-5, Toluca 50200, Estado Mxico, Mexico
[3] Univ Autonoma Chapingo, CONACYT, Lab Nacl Invest, Texcoco De Mora, Mexico
[4] Univ Autonoma Chapingo, CONACYT, Serv Agroalimentario Forestal, Texcoco De Mora, Mexico
关键词
cross-coupling; dehydrogenation; hydrogen storage; hydrogenation; pincer compounds; SELECTIVE ELECTROCATALYTIC REDUCTION; LOW-PRESSURE HYDROGENATION; OXIDANT-FREE CONVERSION; CARBOXYLIC-ACID SALTS; GAMMA-AMINO-ALCOHOLS; CARBON-DIOXIDE; LIGAND COOPERATION; HIGHLY EFFICIENT; SUZUKI-MIYAURA; BASE-FREE;
D O I
10.1002/cctc.201702019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pincer complexes are useful tools for organic synthesis. Their high stability and easy functionalization have allowed the development of novel catalytic systems that have had a tremendous impact in different areas of chemistry. Thus, catalytic reactions are nowadays a fundamental part of several synthetic routes, as they allow greener procedures with high atom efficiency. In this context, pincer complexes have contributed to the establishment of novel and efficient catalytic reactions. Thus, herein we summarize the most recent relevant advances involving pincer complexes as catalysts.
引用
收藏
页码:3136 / 3172
页数:37
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