Membrane application in Fischer-Tropsch synthesis to enhance CO2 hydrogenation

被引：69

作者：

Rohde, MP ^{[1
]}

Unruh, D ^{[1
]}

Schaub, G ^{[1
]}

机构：

[1] Univ Karlsruhe TH, Engler Bunte Inst, Bereich Gas Erdol & Kohle, D-76131 Karlsruhe, Germany

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2005年 / 44卷 / 25期

关键词：

D O I：

10.1021/ie050289z

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The present work experimentally demonstrates that the conversion of CO2 to long-chain hydrocarbons via CO2 shift and Fischer-Tropsch reaction can be enhanced by in situ H2O removal. The experiments are carried out in a packed-bed reactor with an integrated silica membrane. Though the membrane exhibits low permselectivities regarding H2O under Fischer-Tropsch conditions, the deficiencies in permselectivity can be overcome by the choice of H-2 and H-2/CO2 as the sweep-gas. The increase in conversion and yield is attributed to the removal of H2O, which is shown by experimental data analysis based on a reaction engineering type model of the inert membrane packed-bed reactor.

引用

页码：9653 / 9658

页数：6

共 50 条

[41] Hydrogenation of CO2 into hydrocarbons: enhanced catalytic activity over Fe-based Fischer-Tropsch catalysts
Jiang, Feng
Liu, Bing
Geng, Shunshun
Xu, Yuebing
Liu, Xiaohao
[J]. CATALYSIS SCIENCE & TECHNOLOGY, 2018, 8 (16) : 4097 - 4107
[42] Fischer-Tropsch principles of CO-hydrogenation on cobalt catalysts.
Schulz, H
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U565 - U565
[43] The effect of CO2 on a cobalt-based catalyst for low temperature Fischer-Tropsch synthesis
Yao, Y.
Liu, X.
Hildebrandt, D.
Glasser, D.
[J]. CHEMICAL ENGINEERING JOURNAL, 2012, 193 : 318 - 327
[44] Role of CO2 in the initiation of chain growth and alcohol formation during the Fischer-Tropsch synthesis
Xu, LG
Bao, SQ
Houpt, DJ
Lambert, SH
Davis, BH
[J]. CATALYSIS TODAY, 1997, 36 (03) : 347 - 355
[45] CO2 Conversion by Fischer-Tropsch Synthesis Using Na-Modified Fe Catalysts
Schmidt, Christian
Kureti, Sven
[J]. CHEMIE INGENIEUR TECHNIK, 2022, 94 (11) : 1747 - 1755
[46] ZR PROMOTION OF CO/SIO2 FOR FISCHER-TROPSCH SYNTHESIS
ALL, S
CHEN, B
GOODWIN, JG
[J]. JOURNAL OF CATALYSIS, 1995, 157 (01) : 35 - 41
[47] CO activation pathways and the mechanism of Fischer-Tropsch synthesis
Ojeda, Manuel
Nabar, Rahul
Nilekar, Anand U.
Ishikawa, Akio
Mavrikakis, Manos
Iglesia, Enrique
[J]. JOURNAL OF CATALYSIS, 2010, 272 (02) : 287 - 297
[48] Recovery and usage of CO2 produced in the Fischer-Tropsch synthesis employing Gibbs energy minimization
Marques, Fernando Henrique
Guirardello, Reginaldo
[J]. FLUID PHASE EQUILIBRIA, 2020, 522
[49] Study of Co/ZrO2 Catalysts in Fischer-Tropsch Synthesis
Zhao, Hongxia
Lu, Hailiang
[J]. ADVANCES IN APPLIED SCIENCES AND MANUFACTURING, PTS 1 AND 2, 2014, 850-851 : 120 - +
[50] Fischer-Tropsch synthesis in supercritical fluid: characteristics and application
Fan, L
Fujimoto, K
[J]. APPLIED CATALYSIS A-GENERAL, 1999, 186 (1-2) : 343 - 354

← 1 2 3 4 5 →