Squaraine [2]catenanes: synthesis, structure and molecular dynamics

被引:15
|
作者
Lee, Jung-Jae [1 ]
Baumes, Jeffrey M. [1 ]
Connell, Richard D. [1 ]
Oliver, Allen G. [1 ]
Smith, Bradley D. [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
关键词
NEAR-IR DYES; BENZYLIC AMIDE; ROTAXANES; PROBES; COMPLEXES; BOND;
D O I
10.1039/c1cc10946d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three squaraine [2]catenanes are synthesized and found to have bright, deep-red fluorescence and high chemical stability. The interlocked molecules undergo two large-amplitude dynamic processes, twisting of the squaraine macrocycle and skipping over the partner tetralactam.
引用
收藏
页码:7188 / 7190
页数:3
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