Insertion of dichlorocarbene into C-B bond of borinates under liquid-liquid phase transfer catalysis conditions: A convenient preparation of unsymmetrical ketones

被引：0
|
作者：
Huang, SW [1 ]
Guo, F
Shan, ZX
Zhao, DJ
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Hubei, Peoples R China
[2] Hubei Polytech Univ, Dept Chem Engn, Wuhan 430068, Hubei, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2001年 / 19卷 / 02期
关键词：
dichlorocarbene; insertion; borinate; phase transfer catalysis; unsymmetrical ketone;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unsymmetrical ketones were conveniently prepared from the unsymmetrical diorganyl borinates via the insertion of dichlorocarbene into C-B bond under Liquid-liquid phase transfer catalysts conditions and oxidation with alkaline hydrogen peroxide in 35-67% yields.
引用
收藏
页码：202 / 204
页数：3
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