Novel promising benzoazacrown ethers as a result of ring transformation of benzocrown ethers:: Synthesis, structure, and complexation with Ca2+

被引：29

作者：

Gromov, SP

Dmitrieva, SN

Vedernikov, AI

Kuz'mina, LG

Churakov, AV

Strelenko, YA

Howard, JAK

机构：

[1] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

[3] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

[4] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 16期

关键词：

crown compounds; podands; cyclization; calcium; NMR spectroscopy;

D O I：

10.1002/ejoc.200300179

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of promising benzoazacrown ethers with the nitrogen atom conjugated with the benzene ring were synthesized using a novel synthetic procedure based on stepwise transformation of the macroheterocycle. The structures and spectral proper-ties of the resulting benzoazacrown ethers and their complexes with Ca2+ were studied by X-ray diffraction and H-1, C-13, and N-15 NMR spectroscopy including the 2D NOESY technique. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

引用

页码：3189 / 3199

页数：11

共 20 条

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