Novel promising benzoazacrown ethers as a result of ring transformation of benzocrown ethers:: Synthesis, structure, and complexation with Ca2+

被引：29

作者：

Gromov, SP

Dmitrieva, SN

Vedernikov, AI

Kuz'mina, LG

Churakov, AV

Strelenko, YA

Howard, JAK

机构：

[1] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

[3] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

[4] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 16期

关键词：

crown compounds; podands; cyclization; calcium; NMR spectroscopy;

D O I：

10.1002/ejoc.200300179

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of promising benzoazacrown ethers with the nitrogen atom conjugated with the benzene ring were synthesized using a novel synthetic procedure based on stepwise transformation of the macroheterocycle. The structures and spectral proper-ties of the resulting benzoazacrown ethers and their complexes with Ca2+ were studied by X-ray diffraction and H-1, C-13, and N-15 NMR spectroscopy including the 2D NOESY technique. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

引用

页码：3189 / 3199

页数：11

共 20 条

[1] New methodology for the synthesis of benzoazacrown ethers by transformation of the macrocycle of benzocrown ethers
S. P. Gromov
S. N. Dmitrieva
A. I. Vedernikov
M. V. Churakova
Russian Chemical Bulletin, 2004, 53 : 1417 - 1427
[2] New methodology for the synthesis of benzoazacrown ethers by transformation of the macrocycle of benzocrown ethers
Gromov, SP
Dmitrieva, SN
Vedernikov, AI
Churakova, MV
RUSSIAN CHEMICAL BULLETIN, 2004, 53 (07) : 1417 - 1427
[3] Synthesis of benzoazacrown ethers by transformation of benzocrown macrocycle and preparation of related complexing agents
Dmitrieva, S. N.
Vedernikov, A. I.
Ushakov, E. N.
Kuz'mina, L. G.
Gromov, S. P.
RUSSIAN CHEMICAL BULLETIN, 2015, 64 (08) : 1726 - 1745
[4] Synthesis of benzoazacrown ethers by transformation of benzocrown macrocycle and preparation of related complexing agents
Dmitrieva S.N.
Vedernikov A.I.
Ushakov E.N.
Kuźmina L.G.
Gromov S.P.
Russian Chemical Bulletin, 2015, 64 (8) : 1726 - 1745
[5] NOVEL SYNTHESIS OF BENZOCROWN ETHERS FORMYLATED IN THE BENZENE-RING
GROMOV, SP
FEDOROVA, OA
VEDERNIKOV, AI
SAMOSHIN, VV
ALFIMOV, MV
RUSSIAN CHEMICAL BULLETIN, 1993, 42 (05) : 960 - 961
[6] Nitro Derivatives of Benzoazacrown Ethers: Synthesis, Structure, and Complexation with Metal and Ammonium Cations and Fluoride Anion
Dmitrieva, Svetlana N.
Kurchavov, Nikolay A.
Kuz'mina, Lyudmila G.
Vedernikov, Artem, I
Churakova, Marina, V
Sazonov, Sergey K.
Howard, Judith A. K.
Gromov, Sergey P.
MACROHETEROCYCLES, 2019, 12 (01): : 82 - 93
[7] BENZOCROWN DERIVATIVES AS IONOPHORES FOR ALKALI CATIONS .3. SYNTHESIS OF RING-CLEAVED ANALOGS OF BENZOCROWN ETHERS A NOVEL METHOD FOR BUILDING UP CROWN ETHER RINGS
TOKE, L
BITTER, I
AGAI, B
HELL, Z
LINDNER, E
TOTH, K
HORVATH, M
SZOLLOSY, A
HARFOUCH, S
PUNGOR, E
LIEBIGS ANNALEN DER CHEMIE, 1988, (08): : 761 - 763
[8] Structural and complexation properties of diselenacrown ethers. Synthesis and crystal structure of a novel cationic palladium tetraselena complex
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Amardeil, R
Meunier, P
Daran, JC
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[9] Synthesis of the novel crown and lariat ethers with integrated 1,2,3-triazole ring
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Jaworski, Przemyslaw
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2017, 192 (02) : 231 - 234
[10] SYNTHESIS OF MEDIUM RING ETHERS .3. DISPROOF OF THE PROPOSED 2,8-DISUBSTITUTED OXOCANE STRUCTURE FOR GLOEOSPORONE - SYNTHESIS OF PSEUDO-GLOEOSPORONE
CARLING, RW
CLARK, JS
HOLMES, AB
SARTOR, D
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (01): : 95 - 101

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