Metal-Free Arylalkylation of N-Aryl Acrylamides with Azobisalkyl-nitriles

被引：11
|
作者：
Tian, Qingshan [1 ]
He, Ping [1 ]
Kuang, Chunxiang [1 ,2 ]
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
[2] Minist Educ, Key Lab Yangtze River Water Environm, Shanghai 200092, Peoples R China
来源：
SYNLETT | 2015年 / 26卷 / 05期
基金：
中国国家自然科学基金;
关键词：
metal-free; aryalkylation; acrylamide; AIBN; oxindole; PALLADIUM-CATALYZED CYANATION; ACTIVATED ALKENES; OXINDOLES; BOND; SILVER; CN; N; N-DIMETHYLFORMAMIDE; FUNCTIONALIZATION; MECHANISM; HALIDES;
D O I：
10.1055/s-0034-1379888
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel metal-free arylalkylation of N-aryl acrylamides with readily available azobisalkylnitriles leading to cyano-containing oxindoles has been developed. The use of readily available azobisalkylnitriles and DTBP as oxidant makes this protocol environmentally benign and practical.
引用
收藏
页码：681 / 687
页数：7
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