ONE-POT, THREE-COMPONENT SYNTHESIS OF α-AMINO PHOSPHONATES USING NaHSO4-SiO2 AS AN EFFICIENT AND REUSABLE CATALYST

被引：18

作者：

Maghsoodlou, Malek Taher ^{[1
]}

Heydari, Reza ^{[1
]}

Habibi-Khorassani, Sayyed Mostafa ^{[1
]}

Hazeri, Nourallah ^{[1
]}

Sajadikhah, Seyed Sajad ^{[1
]}

Rostamizadeh, Mohsen ^{[1
]}

Lashkari, Mojtaba ^{[1
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, Fac Sci, Zahedan, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 01期

关键词：

alpha-Amino phosphonates; heterogeneous catalyst; NaHSO4-SiO2; reusable catalyst; trialkylphosphite; ORGANIC PHOSPHORUS-COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; ACID; INHIBITORS; AMINOPHOSPHONATES; ALDEHYDES; PROTOCOL; WELL;

D O I：

10.1080/00397911.2010.523153

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, efficient, and environmentally benign method has been developed for the synthesis of alpha-amino phosphonates. One-pot, three-component reaction of aldehyds, amines, and trialkylphosphite in the presence of silica-supported sodium hydrogen sulfate (NaHSO4-SiO2) as an inexpensive and reusable catalyst under solvent-free conditions at 80 degrees C affords the corresponding a-amino phosphonates in good yields and short reaction times.

引用

页码：136 / 143

页数：8

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