SYNTHESIS, CHARACTERIZATION, COMPUTATIONAL STUDIES AND SINGLE CRYSTAL STRUCTURES OF [Ru(N-P)2(O-O)] COMPLEXES

被引：2

作者：

Al-Wahish, M. A. ^{[1
]}

Awwadi, F. F. ^{[1
]}

Hodali, H. A. ^{[1
]}

机构：

[1] Univ Jordan, Fac Sci, Dept Chem, Amman, Jordan

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 62卷 / 07期

关键词：

8-diphenylphosphinoquinoline; ruthenium complexes; oxalate; malonate; 1,1-cyclobutandicarboxylate; SPECTROSCOPIC PROPERTIES; RUTHENIUM(II) COMPLEXES; 8-(DIPHENYLPHOSPHINO)QUINOLINE; BPY=2,2'-BIPYRIDINE; CATALYSTS;

D O I：

10.1134/S002247662107009X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complexes [Ru(N-P)(2)(O-O)] (N-P = (8-diphenylphosphino)quinoline, O-O = dianion of oxalate (1), malonate (2) or 1,1-cyclobutandicarboxylate (3)), are prepared from [Ru(N-P)(2)Cl-2] by a reaction with potassium salt of oxalate, malonate, or cyclobutandicarboxylate, respectively. All the complexes have distorted octahedral structures. Complex 1 crystallizes in the monoclinic system with space groups P2(1)/c. On the other hand, complexes 2 and 3 crystallizes in the triclinic system with the space group P-1. The UV-Vis spectra of the three complexes are modeled using time dependent density function theory (TD-DFT).

引用

页码：1056 / 1065

页数：10

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