Crystal structure of catena-(μ4-1,3-diethyl-2-thiobarbiturato-O,O',S,S)silver(I)

被引：9
|
作者：
Golovnev, N. N. [1 ]
Molokeev, M. S. [2 ,3 ]
Lutoshkin, M. A. [1 ]
机构：
[1] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[2] Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
[3] Far Eastern State Univ Railway Res, Khabarovsk 680021, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 05期
关键词：
1,3-DIETHYL-2-THIOBARBITURIC ACID; HYDROGEN-BOND; COMPLEXES; SERIES; NA; LI;
D O I：
10.1134/S0036023615050071
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of catena-(mu(4)-1,3-diethyl-2-thiobarbiturato-O,O',S,S)silver(I) [Ag(mu(4)-DETBA-O,O',S,S] (1), where HDETBA is 1,3-diethyl-2-thiobarbituric acid C8H12N2O2S, has been solved by X-ray powder diffraction. Crystals of complex 1 are monoclinic, a = 7.8339(2) , b = 15.4970(4) , c = 8.7502(2) , beta = 111.916(2)A degrees, V = 985.53(5) (3), space group P2(1)/c, Z = 4. The Ag+ ion is coordinated by two oxygen atoms and two sulfur atoms to form a distorted tetrahedron. Tetrahedra share sulfur atom vertices to form infinite chains linked via bridging DETBA(-) ions into a three-dimensional framework. No hydrogen bonds have been found in the structure, but pi-pi interaction is observed between DETBA(-) ions.
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收藏
页码：572 / 576
页数：5
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