Synthesis and crystal structure of (NH4)(3)Cu4Ho2Br13. Further bromides of the (NH4)(3)Cu(4)M(2)Br(13) type (M=Dy-Lu, Y) and on Rb3Cu4Ho2Br13

被引：2

作者：

Wickleder, MS ^{[1
]}

Bohnsack, A ^{[1
]}

Meyer, G ^{[1
]}

机构：

[1] SONDERFORSCH BEREICH 173,HANNOVER,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 04期

关键词：

rare earths; bromides; copper; synthesis; crystal structure;

D O I：

10.1002/zaac.19966220417

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of (NH4)(3)Cu4Ho2Br13 were obtained for the first time from the reaction of CuBr with HoBr3 which was contaminated with NH4Br: cubic, space group Pn(3) over bar, Z = 2, a = 1101.71(5)pm. The crystal structure may be considered as a variant of the fluorite type according to [(HoBr6)(4)][(NH4)(6)(Cu4Br)2] = Ca4F8. Pure products can be prepared from the binary halides in glass ampoules at 350 degrees C. The bromides (NH4)(3)Cu(4)M(2)Br(13) (M = Dy-Lu, Y) and Rb3Cu4Ho2Br13 are isotypic with (NH4)(3)Cu4Ho2Br13.

引用

页码：675 / 678

页数：4

共 50 条

[41] ELECTRON-PARAMAGNETIC RESONANCE STUDY OF CU(II) IN THE CU(II) DOPED (NH4)2[ZN(NH3)2(CRO4)2] AND (NH4)2[CD(NH3)2(CRO4)2] - ORIENTATIONAL DISORDER OF NH3 AND DYNAMICALLY INDUCED STRUCTURAL-CHANGE
WANG, DM
KOVACIK, I
REIJERSE, EJ
DEBOER, E
JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (06): : 3897 - 3904
[42] PHASE-RELATIONS IN THE SYSTEM NH4ZR2(PO4)3-(NH4)3M2(PO4)3 - M = Y, AL OR IN
ONO, A
JOURNAL OF MATERIALS SCIENCE LETTERS, 1985, 4 (08) : 936 - 939
[43] NH4CU4BR3+XI2-X CONDUCTORS WITH RAPID-TRANSPORT OF COPPER IONS
SHVETSOV, VS
IVANOV, VV
INORGANIC MATERIALS, 1990, 26 (08) : 1479 - 1481
[44] Synthesis and crystal structure of (CH3NH3)2[Cu(NO3)4]:: a rare example of a tetranitratocuprate(II) with a light cation of the type M2[Cu(NO3)4]
Steinhauser, Georg
Karaghiosoff, Konstantin
Klapoetke, Thomas M.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (05): : 892 - 894
[45] ESR AND OPTICAL-SPECTRA OF CU2+-NH4BR
TRAPPENIERS, NJ
STIBBE, FS
RAO, JL
CHEMICAL PHYSICS LETTERS, 1978, 56 (01) : 10 - 14
[46] 是[Cu（NH3）4]SO4还是[Cu（NH3）4]（OH）2?
蒋树源
化学教育, 1987, (05) : 53 - 55
[47] THESYNTHESISANDCRYSTALSTRUCTUREOFANOVELMOLYBDENUM-SULFURCLUSTERCOMPLEX,（NH4）4[Mo3（NO）4S13]·3H2O
汤卡罗
金祥林
唐有祺
Science in China,SerB., 1984, Ser.B.1984 (07) : 657 - 664
[48] Synthesis and structure of hydrogen sulfates of the type M(HSO4)(H2SO4) (M=Rb,Cs and NH4)
Werner, C
Trojanov, S
Kemnitz, E
Worzala, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (02): : 380 - 384
[49] Synthesis and Structure of Hydrogen Sulfates of the Type M(HSO4)(H2SO4) (M = Rb, Cs, and NH4)
Werner, C.
Trojanov, S.
Kemnitz, E.
Worzala, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 622 (02):
[50] Action of ammonium fluoride on scandium:: Synthesis and crystal structures of (NH4)3[ScF6] and [Cu(NH3)4]3[ScF6]2
Böhmer, N
Meyer, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (06): : 1248 - 1252

← 1 2 3 4 5 →