Spectroscopic study of nitrogen doping of multi-walled carbon nanotubes

被引:9
|
作者
Enouz, S.
Bantignies, J. L.
Babaa, M. R.
Alvarez, L.
Parent, P.
Le Normand, F.
Stephan, O.
Poncharal, P.
Loiseau, A.
Doyle, B. P.
机构
[1] Univ Montpellier 2, Lab Colloides Verres & Nanomat, F-34095 Montpellier, France
[2] LEM, ONERA CNRS UMR 104, F-93322 Chatillon, France
[3] Univ Paris 11, Lab Chim Phys Mat & Rayonnement, F-91405 Orsay, France
[4] Inst Phys & Chim Mat IPCMS, UMR CNRS 7504, F-67034 Strasbourg, France
[5] Univ Paris 11, LPS, F-91405 Orsay, France
[6] CNR, INFM, Lab Nazl TASC, I-34012 Basovizza, TS, Italy
关键词
NEXAFS; nanotubes; nitrogen;
D O I
10.1166/jnn.2007.839
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Combined spatially resolved electron-energy loss spectroscopy (EELS) and high resolution near-edge X-ray absorption fine structure (NEXAFS) spectroscopy have been used to investigate the nitrogen doping of multi-walled carbon nanotubes (N-MWNT). EELS indicates that most of the tubes are nitrogen-doped. NEXAFS spectroscopy reveals pyridine-like and nitrile N structures. High resolution NEXAFS experiments show that the main nitrogen concentration originates from a high amount of molecular N-2 encapsulated into only a small quantity of tubes.
引用
收藏
页码:3524 / 3527
页数:4
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