Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor

被引：96
|
作者：
Huang, Wenyu
Liu, Jack Hung-Chang
Alayoglu, Pinar
Li, Yimin
Witham, Cole A.
Tsung, Chia-Kuang
Toste, F. Dean [1 ]
Somorjai, Gabor A.
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 47期
关键词：
ORGANIC-SYNTHESIS; HYDROGENATION; PD;
D O I：
10.1021/ja108898t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly active heterogeneous Pd-nanoparticle catalyst for the intramolecular addition of phenols to alkynes was developed and employed in a continuous flow reaction system. Running the reaction in flow mode revealed reaction kinetics, such as the activation energy and catalyst deactivation, and provides many potential practical advantages.
引用
收藏
页码：16771 / 16773
页数：3
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