A perylene bisimide network for high-performance n-type electrochromism

被引：61
|
作者：
Ma, Weitao [1 ]
Qin, Leiqiang [1 ]
Gao, Yu [2 ]
Zhang, Wenqiang [2 ]
Xie, Zengqi [1 ]
Yang, Bing [2 ]
Liu, Linlin [1 ]
Ma, Yuguang [1 ]
机构：
[1] South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 93期
基金：
中国国家自然科学基金;
关键词：
POLYMERS; GREEN; REDOX;
D O I：
10.1039/c6cc07962h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical anion) state and further to an aquamarine (dianion) state. The film possesses preferable coloration efficiency and cycling stability (410000 cycles).
引用
收藏
页码：13600 / 13603
页数：4
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