Process intensification for tertiary amine catalyzed glycerol carbonate production: translating microwave irradiation to a continuous-flow process

被引：28
|
作者：
Nogueira, Daniel O. [1 ]
de Souza, Stefania P. [1 ]
Leao, Raquel A. C. [1 ]
Miranda, Leandro S. M. [1 ]
de Souza, Rodrigo O. M. A. [1 ]
机构：
[1] Univ Fed Rio de Janeiro, Biocatalysis & Organ Synth Grp, Inst Chem, BR-21941909 Rio De Janeiro, RJ, Brazil
来源：
RSC ADVANCES | 2015年 / 5卷 / 27期
关键词：
DIMETHYL CARBONATE; IONIC-LIQUID; OXIDATIVE CARBONYLATION; EFFICIENT SYNTHESIS; LANTHANUM OXIDE; BY-PRODUCT; TRANSESTERIFICATION; UREA; BIODIESEL; LIPASE;
D O I：
10.1039/c5ra02117k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Different products of interest can be produced from glycerol and glycerol carbonate (GC) has received much attention in recent years because of its physical properties, nontoxicity and water solubility. Herein we report a process intensification protocol for glycerol carbonate production mediated by tertiary amine catalysis where a 24 kg per L per day productivity was obtained with 79% isolated yield and a 5 hour operation time without losing efficiency.
引用
收藏
页码：20945 / 20950
页数：6
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