Model Studies for the Preparation of Oxepanes and Fused Compounds by Tandem [4+3] Cycloaddition/Ring-Opening Metathesis/Cross Metathesis

被引：3

作者：

Disetti, Paolo ^{[1
]}

Piras, Linda ^{[2
]}

Moccia, Maria ^{[2
]}

Saviano, Michele ^{[2
]}

Adamo, Mauro F. A. ^{[1
]}

机构：

[1] Royal Coll Surgeons Ireland, CSCB, Dept Pharmaceut & Med Chem, 123 St Stephens Green, Dublin 2, Ireland

[2] CNR, Inst Crystallog, Via G Amendola 122-O, I-70126 Bari, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 41期

基金：

欧盟地平线“2020”;

关键词：

Cycloaddition; Metathesis; Alkenes; Cyclic ethers; Polycycles; Fused-ring systems; PTYCHODISCUS-BREVIS; GAMBIERIC ACIDS; RINGS; GYMNODINIUM; 1,3-DIENES; SYSTEMS; ETHERS;

D O I：

10.1002/ejoc.201700994

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalised medium-sized ether rings were prepared in an efficient manner by [4+3] cycloaddition followed by ring-opening metathesis. This procedure provided medium-sized rings, which were shown to be useful for the assembly of fused bicyclic structures present in complex natural compounds. The potential of the chemistry described in this paper to be used in synthesis has been demonstrated by the preparation of functionalised large cyclic ethers and bicyclic structures.

引用

页码：6202 / 6208

页数：7

共 50 条

[1] Tandem catalytic asymmetric ring-opening metathesis/cross metathesis
La, DS
Ford, JG
Sattely, ES
Bonitatebus, PJ
Schrock, RR
Hoveyda, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) : 11603 - 11604
[2] Tandem catalytic asymmetric ring-opening metathesis/ring-closing metathesis
Weatherhead, GS
Ford, JG
Alexanian, EJ
Schrock, RR
Hoveyda, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (08) : 1828 - 1829
[3] Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization
Suriboot, Jakkrit
Bazzi, Hassan S.
Bergbreiter, David E.
[J]. POLYMERS, 2016, 8 (04)
[4] Hybrid Polymerization of Ring-Opening Metathesis and Cross-Metathesis for Polyolefins with Tunable Architectures
Ren, Ning
Zhuo, Xinyuan
[J]. MACROMOLECULES, 2018, 51 (23) : 9555 - 9561
[5] RING-OPENING METATHESIS POLYMERIZATION OF EXODICYCLOPENTADIENE - REVERSIBLE CROSS-LINKING BY A METATHESIS CATALYST
FISHER, RA
GRUBBS, RH
[J]. MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 63 : 271 - 277
[6] Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions and Z-Selective Ring-Opening Metathesis Polymerization
Cordova, Armando
Rios, Ramon
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) : 8827 - 8831
[7] PREPARATION OF POLYDELTACYCLENE VIA RING-OPENING METATHESIS AND POLYMER REACTIVITY
LAUTENS, M
ABDELAZIZ, AS
SCHMIDT, G
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 481 - INOR
[8] PREPARATION OF STAR POLYMERS BY LIVING RING-OPENING METATHESIS POLYMERIZATION
BAZAN, G
SCHROCK, RR
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 307 - INOR
[9] Preparation of luminescent lanthanide polymers by ring-opening metathesis polymerization
Yoon, Myeong Sik
Santra, Mithun
Ahn, Kyo Han
[J]. TETRAHEDRON LETTERS, 2015, 56 (41) : 5573 - 5577
[10] Preparation and Performances of Degradable Polybenzoxazine by Ring-Opening Metathesis Polymerization
Wang, Weiwei
Jiang, Jin
An, Qinglong
Shi, Rui
Shao, Shuyang
Wang, Zhi
[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (39) : 14622 - 14632

← 1 2 3 4 5 →