RING-OPENING METATHESIS POLYMERIZATION OF EXODICYCLOPENTADIENE - REVERSIBLE CROSS-LINKING BY A METATHESIS CATALYST

被引：39
|
作者：
FISHER, RA [1 ]
GRUBBS, RH [1 ]
机构：
[1] CALTECH,ARNOLD & MABEL BECKMAN LABS CHEM SYNTH,PASADENA,CA 91125
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 63卷
关键词：
D O I：
10.1002/masy.19920630120
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
exo-Dicyclopentadiene has been polymerized by several well characterized, single-component metathesis catalysts to provide soluble, linear, poly exo-dicyclopentadiene. Under the best circumstances the polymerizations proceed in a living manner. The crosslinking of polymer chains which can occur under high monomer concentration has been investigated and determined to result from the secondary metathesis of the cyclopentene substituent.
引用
收藏
页码：271 / 277
页数：7
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