Metal-organic framework ZIF-8 loaded with rhodium nanoparticles as a catalyst for hydroformylation

被引：6

作者：

Vlasenko, Ekaterina S. ^{[1
,2
]}

Nikovskiy, Igor A. ^{[1
]}

V. Nelyubina, Yulia ^{[1
]}

Korlyukov, Alexander A. ^{[1
]}

V. Novikov, Valentin ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Natl Res Univ Higher Sch Econ, Moscow 101000, Russia

来源：

MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

hydroformylation; metal-organic frameworks; reaction vessel; catalyst; rhodium nanoparticles; MOFS;

D O I：

10.1016/j.mencom.2022.05.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous metal-organic framework ZIF-8 materials containing incorporated rhodium (Rh@ZIF-8) and rhodium chloride (RhCl3@ZIF-8) nanoparticles were obtained and tested as a catalytic reaction vessel in the reactions of hydroformylation of 1-decene and styrene. Catalytic tests with Rh@ZIF-8 showed that the selectivity and conversion of the hydroformylation reaction depended on the size of the substrate molecule. The incorporation of catalytic nanoparticles into the pores of a metal-organic framework opens up new possibilities for regioselective hydroformylation.

引用

页码：320 / 322

页数：3

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