Engineering carbene rearrangements in crystals: From molecular information to solid-state reactivity

被引：122
|
作者：
Garcia-Garibay, MA [1 ]
机构：
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2003年 / 36卷 / 07期
关键词：
D O I：
10.1021/ar970309w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Although severely restricted, reactions in crystals have delivered some of the most impressive examples of chemical control and provided an ideal medium for detailed mechanistic studies. However, to take full advantage of their potential and avoid their shortcomings, a systematic approach for the reliable design of reaction in crystals is required. To that end, strategies based on structural and energetic information contained at the molecular level have been explored with reactions involving carbene rearrangements.
引用
收藏
页码：491 / 498
页数：8
相关论文
共 50 条
  • [1] Engineering reactions in crystalline solids: From molecular information to solid-state reactivity
    Garcia-Garibay, Miguel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [2] Solid-State NMR Studies of Molecular Crystals
    Dudek, Marta K.
    Kazmierski, Slawomir
    Kostrzewa, Maciej
    Potrzebowski, Marek J.
    ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 95, 2018, 95 : 1 - 81
  • [3] Solid-state reactions, dynamics in molecular crystals
    Kaupp, G
    CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2002, 6 (02): : 131 - 138
  • [4] Engineering the solid-state luminescence of organic crystals and cocrystals
    Dar, Aijaz A.
    Lone, Shaista H.
    Ahmad, Ishtiyaq
    Ahangar, Aadil A.
    Ganie, Arshid A.
    Femina, Cherumannil
    MATERIALS ADVANCES, 2024, 5 (03): : 1056 - 1064
  • [5] PRESSURE-INDUCED MOLECULAR-REARRANGEMENTS IN THE SOLID-STATE
    DRICKAMER, HG
    BRAY, KL
    INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1989, 8 (01) : 41 - 64
  • [6] Molecular control of solid-state reactivity and biradical formation from crystalline ketones
    Choi, T
    Peterfy, K
    Khan, SI
    GarciaGaribay, MA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (49) : 12477 - 12478
  • [7] Solid-State Reactivity in Halogen-Bonded Co-Crystals.
    Metrangolo, Pierangelo
    Biella, Serena
    Cavallo, Gabriella
    Pilati, Tullio
    Resnati, Giuseppe
    Terraneo, Giancarlo
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S91 - S91
  • [8] Supramolecular assembly of conjugated polymers:: From molecular engineering to solid-state properties
    Leclere, Ph.
    Surin, M.
    Brocorens, P.
    Cavallini, M.
    Biscarini, F.
    Lazzaroni, R.
    MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2006, 55 (1-2): : 1 - 56
  • [9] SOLID-STATE REACTIVITY OF TRIACETYLENES
    ENKELMANN, V
    CHEMISTRY OF MATERIALS, 1994, 6 (08) : 1337 - 1340
  • [10] From engineering crystals to engineering molecules: emergent consequences of controlling reactivity in the solid state using linear templates
    McGillivray, LR
    CRYSTENGCOMM, 2002, 4 (07): : 1 - 10
12345