SOLID-STATE REACTIVITY OF TRIACETYLENES

被引：61
|
作者：
ENKELMANN, V
机构：
[1] Max-Planck-Institut für Polymerforschung, Postfach 3148
来源：
CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 08期
关键词：
D O I：
10.1021/cm00044a035
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Crystal structures of four triacetylenes are reported. Three of the investigated monomers polymerize in the solid state. In all of these cases the polymerization proceeds by a 1,4 addition and is a nonunique topochemical reaction. Therefore, the reactions are not single-crystal-to-single-crystal processes. Possible strategies for the design of reactive triacetylenes undergoing 1,6 addition in the solid state are discussed.
引用
收藏
页码：1337 / 1340
页数：4
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