[2,6-Bis(diphenylphosphanyloxy)phenyl-κ3P,C1,P′]hydroxidonickel(II)

被引：7
|
作者：
Zargarian, Davit [1 ]
Salah, Abderrahmen [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1107/S1600536811014267
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecule of the title complex, [Ni(C30H23O2P2)(OH)], adopts a slightly distorted square-planar geometry around Ni-II defined by the coordination of the two mutually trans P atoms, the Csp(2) atom of the pincer ligand and the O atom of the hydroxide ligand. The largest distortions from ideal geometry are reflected in the smaller than usual P-Ni-P [163.95 (3)degrees] and P-Ni-C [82.06 (6)degrees] angles. The OH ligand does not form intra- or intermolecular hydrogen bonds.
引用
收藏
页码：M940 / U1124
页数：11
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