Enantioselective oxidation of sulfides to sulfoxides catalysed by bacterial cyclohexanone monooxygenases

被引：88
|
作者：
Colonna, S [1 ]
Gaggero, N [1 ]
Pasta, P [1 ]
Ottolina, G [1 ]
机构：
[1] CNR,IST CHIM ORMONI,I-20131 MILAN,ITALY
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 20期
关键词：
D O I：
10.1039/cc9960002303
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review article briefly introduces the applications of bacterial cyclohexanone monooxygenases to the enantioselective oxidations of organic sulfur compounds to sulfoxides, High enantioselectivities are observed in the sulfoxidation of alkyl aryl sulfides, disulfides, dialkyl sulfides, cyclic and acyclic 1,3-dithioacetals, The oxidation of ail;yl aryl sulfides with flavin dependent microorganisms extends the synthetic interest of this class of enzymes.
引用
收藏
页码：2303 / 2307
页数：5
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