On the spectroscopy of Bi3+ in d10 post-transition metal oxides

被引：29
|
作者：
Boutinaud, Philippe [1 ]
机构：
[1] Clermont Univ Auvergne, SIGMA Clermont, Inst Chim Clermont Ferrand, BP 10448, F-63000 Clermont Ferrand, France
来源：
JOURNAL OF LUMINESCENCE | 2020年 / 223卷
关键词：
Bi3+; Charge transfer; d(10) post-transition metals; Oxide compounds; PERSISTENT LUMINESCENCE; ENERGY; ION; SN;
D O I：
10.1016/j.jlumin.2020.117219
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The optical spectroscopy of Bi3+ in d(10)-based post transition metal oxides (i. e. gallates, germanates, antimonates indates, stannates) is reviewed and analyzed in the frame of empirical models. 20 different compounds are examined. From this, a methodology is introduced to identify the preferred doping sites for Bi3+ and predict the intra- or extra-ionic origin of the Bi3+ emission in these systems. Further, the emission process in calcitestructured InBO3:Bi and GaBO3:Bi is reconsidered.
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页数：8
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