Relativistic effects in oxides and halides of transition and post-transition metals

被引：0
|
作者：
S. G. Kozlova
M. R. Ryzhikov
V. A. Slepkov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
relativistic effects; electronic structure; polymorphism; magnetism; stereochemically active lone pairs;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The review presents the experimental and theoretic data on relativistic effects in solids, which were the objects of S. P. Gabuda’s studies. Coordination and cluster compounds are considered. Unique data obtained by nuclear magnetic resonance, vibrational spectroscopy, magnetochemistry and other methods are presented. The possibilities of the occurrence of polymorphic phase transitions, the Jahn–Teller effect, intermolecular interactions, and other effects due to the features of structure of relativistic wave functions are discussed.
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页码：238 / 256
页数：18
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