Water-soluble Pt3S2 cluster with phosphine ligands

被引：14
|
作者：
Sokolov, Maxim N. [1 ,2 ]
Anyushin, Alexander V. [1 ,2 ]
Virovets, Alexander V. [1 ]
Mirzaeva, Irina V. [1 ]
Zakharchuk, Nina F. [1 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Nikolayev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 10期
关键词：
Platinum complexes; Sulfide clusters; Water-soluble phosphines; Crystal structures; CRYSTAL; COMPLEXES;
D O I：
10.1016/j.inoche.2011.06.033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [Pt(P(CH2OH)(3))(2)Cl-2] with H2S in methanol produces new water-soluble trinuclear complex [Pt-3(mu(3)-S)(2)(P(CH2OH)(3))(6)]Cl-2 (1). It was characterized by IR-spectroscopy, P-31 NMR. X-ray structure analysis, mass-spectra and cyclic voltammetry. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1659 / 1660
页数：2
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