Bimetallic aluminium(acen) complexes as catalysts for the synthesis of cyclic carbonates from carbon dioxide and epoxides

被引：75
|
作者：
North, Michael [1 ]
Young, Carl
机构：
[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 01期
关键词：
SCHIFF-BASE COMPLEXES; ENANTIOSELECTIVE CONJUGATE ADDITIONS; ASYMMETRIC CYANOHYDRIN SYNTHESIS; MINI-CONTINUOUS FLOW; ALPHA; BETA-UNSATURATED KETONES; CRYSTAL-STRUCTURE; SALEN COMPLEXES; ALDOL REACTIONS; CO2; COPOLYMERIZATION;
D O I：
10.1039/c0cy00023j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The development of bimetallic mu-oxoaluminium(acen) complexes as highly active catalysts for the synthesis of cyclic carbonates from terminal epoxides and carbon dioxide is described. The resulting homogeneous catalysts are used in batch reactions for the synthesis of cyclic carbonates at room temperature and one atmosphere pressure.
引用
收藏
页码：93 / 99
页数：7
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