共 50 条
A bifunctional Zn(II)-MOF as recyclable luminescent sensor for detecting TNT and Fe3+ with high selectivity and sensitivity
被引:26
|作者:
Dong, Shengju
[1
]
Hu, Jinsong
[1
,2
,3
]
Zhang, Xiaolong
[1
]
Zheng, Mingdong
[1
]
机构:
[1] Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Peoples R China
[2] Chinese Acad Sci, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Beijing, Peoples R China
[3] Chinese Acad Sci, TIPC, Key Lab Photochem Convers & Optoelect Mat, Beijing, Peoples R China
关键词:
Zn(II)-MOF;
Recyclability;
TNT;
Fe(III);
Selectivity and sensitivity;
METAL-ORGANIC FRAMEWORK;
NITROAROMATIC EXPLOSIVES;
FLUORESCENT CHEMOSENSOR;
CO2;
CAPTURE;
SITES;
IONS;
MOF;
ADSORPTION;
PLATFORM;
POLYMER;
D O I:
10.1016/j.inoche.2018.09.039
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
A znic fluorescence framework {[(Zn-2(BDPO)center dot 3H(2)O]center dot H2O}(n) (1) (H4BDPO = N,N'-Bis(3,5-discarboxyphenyl)oxalamide) was successfully synthesized and characterized. Complex 1 is a 2D sheet [Zn-2(BDPO)](n) the H-bondings and pi center dot center dot center dot pi interactions extend the 2D sheet into 3D supermolecular framework. Importantly, it is a rarely reported highly selective and sensitive luminescence MOF sensor for detecting 2,4,6-Trinitroluene(TNT) and Fe(III) simultaneously through fluorescence quenching. Furthermore, the sensing mechanisms are mainly attributed to the photo-induced electron transfer and competitive absorptions between the excitation/emission of 1 and analytes.
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页码:180 / 186
页数:7
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