A bifunctional Zn(II)-MOF as recyclable luminescent sensor for detecting TNT and Fe3+ with high selectivity and sensitivity

被引:26
|
作者
Dong, Shengju [1 ]
Hu, Jinsong [1 ,2 ,3 ]
Zhang, Xiaolong [1 ]
Zheng, Mingdong [1 ]
机构
[1] Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Peoples R China
[2] Chinese Acad Sci, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Beijing, Peoples R China
[3] Chinese Acad Sci, TIPC, Key Lab Photochem Convers & Optoelect Mat, Beijing, Peoples R China
关键词
Zn(II)-MOF; Recyclability; TNT; Fe(III); Selectivity and sensitivity; METAL-ORGANIC FRAMEWORK; NITROAROMATIC EXPLOSIVES; FLUORESCENT CHEMOSENSOR; CO2; CAPTURE; SITES; IONS; MOF; ADSORPTION; PLATFORM; POLYMER;
D O I
10.1016/j.inoche.2018.09.039
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A znic fluorescence framework {[(Zn-2(BDPO)center dot 3H(2)O]center dot H2O}(n) (1) (H4BDPO = N,N'-Bis(3,5-discarboxyphenyl)oxalamide) was successfully synthesized and characterized. Complex 1 is a 2D sheet [Zn-2(BDPO)](n) the H-bondings and pi center dot center dot center dot pi interactions extend the 2D sheet into 3D supermolecular framework. Importantly, it is a rarely reported highly selective and sensitive luminescence MOF sensor for detecting 2,4,6-Trinitroluene(TNT) and Fe(III) simultaneously through fluorescence quenching. Furthermore, the sensing mechanisms are mainly attributed to the photo-induced electron transfer and competitive absorptions between the excitation/emission of 1 and analytes.
引用
收藏
页码:180 / 186
页数:7
相关论文
共 50 条
  • [1] A bifunctional luminescent coordination polymer as recyclable sensor for detecting TNP and Fe3+ with high selectivity and sensitivity
    Zhang, Xiaolong
    Hu, Jinsong
    Li, Jinsong
    Liu, Tingting
    Wang, Jie
    Ma, Xiangmei
    [J]. INORGANICA CHIMICA ACTA, 2019, 486 : 556 - 561
  • [2] A Mg(II)-MOF as recyclable luminescent sensor for detecting TNP with high selectivity and sensitivity
    Dong, Shengju
    Hu, Jinsong
    Wu, Ke
    Zheng, Mingdong
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 95 : 111 - 116
  • [3] A luminescent Cd(II)-MOF as recyclable bi-responsive sensor for detecting TNP and iron(III)/silver(I) with high selectivity and sensitivity
    Hu, Jinsong
    Wu, Ke
    Dong, Shengju
    Zheng, Mingdong
    [J]. POLYHEDRON, 2018, 153 : 261 - 267
  • [4] A new 8-connected Cd(II)-MOF as luminescent sensor for Fe3+
    Deng, Xiangning
    Li, Yanhua
    He, Yuan-Chun
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2023, 155
  • [5] A Highly Sensitive and Recyclable Ln-MOF Luminescent Sensor for the Efficient Detection of Fe3+ and CrVI Anions
    Li, Xiao
    Tang, Jixin
    Liu, Han
    Gao, Kuan
    Meng, Xiangru
    Wu, Jie
    Hou, Hongwei
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2019, 14 (20) : 3721 - 3727
  • [6] Bifunctional luminescent Eu metal-organic framework for sensing nitroaromatic pollutants and Fe3+ ion with high sensitivity and selectivity
    Li, Zhipeng
    Zhu, Xiaopeng
    Gao, Enjun
    Wu, Shuangyan
    Zhang, Ying
    Zhu, Mingchang
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 35 (03)
  • [7] A bi-functional luminescent Zn(II)-MOF for detection of nitroaromatic explosives and Fe3+ ions
    Du, Jian-Long
    Zhang, Xiao-Ying
    Li, Chao-Ping
    Gao, Ju-Ping
    Hou, Jin-Xin
    Jing, Xu
    Mu, Ya-Juan
    Li, Li-Jun
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 257 : 207 - 213
  • [8] A porous luminescent Zn-MOF for selective probing Fe3+ and nitrophenolic compounds
    Xu, Zhouqing
    Su, Meijie
    He, Xinglei
    Zhang, Bo
    Wang, Yuan
    Li, Huijun
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 111
  • [9] A Zn(II) luminescent polymer as a multifunctional sensor to nitrobenzene, Fe3+ and CrO42- ions
    Wang, Jun
    Lu, Lu
    Wu, Wei-Ping
    Hu, Huai-Ming
    Xie, Bin
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (19) : 2872 - 2880
  • [10] Construction of a dual-response luminescent metal-organic framework with excellent stability for detecting Fe3+ and antibiotic with high selectivity and sensitivity
    Guo, Feng
    Su, Changhua
    Fan, Yuhang
    Shi, Wenbing
    Zhang, Xiuling
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2020, 284