A Zn(II) luminescent polymer as a multifunctional sensor to nitrobenzene, Fe3+ and CrO42- ions

被引:12
|
作者
Wang, Jun [1 ,2 ]
Lu, Lu [1 ]
Wu, Wei-Ping [1 ]
Hu, Huai-Ming [2 ]
Xie, Bin [1 ]
机构
[1] Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Zigong, Peoples R China
[2] Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian, Peoples R China
关键词
Luminescent sensing; topology; structure; METAL-ORGANIC FRAMEWORKS; HIGHLY SELECTIVE DETECTION; FLUORESCENT SENSOR; REVERSIBLE DETECTION; CRYSTAL-STRUCTURE; EXPLOSIVES; INTERPENETRATION; ENCAPSULATION; BEHAVIOR;
D O I
10.1080/00958972.2016.1227438
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A metal-organic framework of {[Zn(tib)(2)]2NO(3)} (tib=135-tris(1-imidazolyl)benzene) (1) has been synthesized and characterized. The structure determination reveals that 1 is a 2-D layer network and exhibits a classical hxl topology. 1 shows selective properties in the detection of nitrobenzene and Fe3+. Furthermore, 1 also exhibits an excellent capability to detect CrO42-. The present work indicates that 1 could be taken as a potential candidate for developing multifunctional luminescence sensors.
引用
收藏
页码:2872 / 2880
页数:9
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