Copper(I) iodide-catalyzed amidation of phenylboronic acids/aryl bromides using 4-dimethylaminopyridine as ligand

被引：8

作者：

Alapati, Mohan Lakshmi Punna Rao ^{[1
,2
]}

Abburu, Sridhar Rao ^{[1
,2
]}

Mutyala, Krishnaji Rao ^{[2
]}

Mukkamala, Saratchandra Babu ^{[1
]}

机构：

[1] GITAM Univ, GITAM Inst Sci, Dept Chem, Visakhapatnam 530045, Andhra Pradesh, India

[2] DIVIS Labs Ltd, Qual Control Dept, Visakhapatnam, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2016年 / 46卷 / 14期

关键词：

Benzamide; copper(I) iodide; 4-dimethylaminopyridine; N-arylbenzamide; phenylboronic acid; ARYL HALIDES; COUPLING REACTIONS; DIAMINE LIGANDS; CUPRIC ACETATE; ENOL TOSYLATES; PALLADIUM; AMIDES; HETEROCYCLES; ARYLATION; ENAMIDES;

D O I：

10.1080/00397911.2016.1195844

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient one-pot synthesis of N-arylbenzamide is described via reaction of phenylboronic acid/aryl bromide with benzamide in the presence of CuI (5mol%) as catalyst, 4-dimethylaminopyridine (20mol%) as the ligand, and Cs2CO3 (2mmol) as the base. This protocol was applied to synthesize a small library of N-arylbenzamide in high yields. [GRAPHICS]

引用

页码：1242 / 1248

页数：7

共 31 条

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