New insights into structural and electrochemical properties of anisotropic polymer electrolytes

被引:21
|
作者
Livshits, E
Kovarsky, R
Lavie, N
Hayashi, Y
Golodnitsky, D [1 ]
Peled, E
机构
[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Wolfson Appl Mat Res Ctr, IL-69978 Tel Aviv, Israel
[3] Hebrew Univ Jerusalem, Dept Appl Phys, IL-91904 Jerusalem, Israel
关键词
polymer electrolyte; conduction properties; magnetic field;
D O I
10.1016/j.electacta.2005.02.047
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The inter-relationship between the orthogonal alignment of polymer helices and improvement of lithium-transport properties of polymer electrolytes has been determined by scanning electron microscopy, differential-scanning calorimetry and dielectric spectroscopy. It is suggested that ordering of the polymer electrolyte accompanied by increased conduction properties is achieved by mutual coordination of local dipole moments of the polar CH2-CH2-O units during casting under a magnetic field. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3805 / 3814
页数:10
相关论文
共 50 条
  • [41] Effect of montmorillonite filler on structural and electrical properties of polymer nanocomposite electrolytes
    Pradhan, Dillip K.
    Choudhary, R. N. P.
    Samantaray, B. K.
    Thakur, Awalendra K.
    Katiyar, R. S.
    IONICS, 2009, 15 (03) : 345 - 352
  • [42] Effect of montmorillonite filler on structural and electrical properties of polymer nanocomposite electrolytes
    Dillip K. Pradhan
    R. N. P. Choudhary
    B. K. Samantaray
    Awalendra K. Thakur
    R. S. Katiyar
    Ionics, 2009, 15 : 345 - 352
  • [43] Effect of plasticizer on structural and electrical properties of nanocomposite solid polymer electrolytes
    Pradhan, Dillip K.
    Samantaray, B. K.
    Choudhary, R. N. P.
    Karan, N. K.
    Thomas, Reji
    Katiyar, R. S.
    IONICS, 2011, 17 (02) : 127 - 134
  • [44] Effect of plasticizer on structural and electrical properties of nanocomposite solid polymer electrolytes
    Dillip K. Pradhan
    B. K. Samantaray
    R. N. P. Choudhary
    N. K. Karan
    Reji Thomas
    R. S. Katiyar
    Ionics, 2011, 17 : 127 - 134
  • [45] New insights into the structural organization of the plant polymer lignin
    Radotic, K
    Micic, M
    Jeremic, M
    BIOPHYSICS FROM MOLECULES TO BRAIN: IN MEMORY OF RADOSLAV K. ANDJUS, 2005, 1048 : 215 - 229
  • [46] Structural and dynamical properties of polymer electrolytes PPO-LiClO4
    Carlsson, P
    Swenson, J
    McGreevy, RL
    Gabrys, B
    Howells, WS
    Borjesson, L
    Torell, LM
    PHYSICA B, 1997, 234 : 231 - 235
  • [47] Structural, thermal and electrochemical cell characteristics of poly(vinyl chloride)-based polymer electrolytes
    Ramesh, S
    Arof, AK
    JOURNAL OF POWER SOURCES, 2001, 99 (1-2) : 41 - 47
  • [48] Reversible Control of Electrochemical Properties Using Thermally-Responsive Polymer Electrolytes
    Kelly, Jesse C.
    Pepin, Mark
    Huber, Dale L.
    Bunker, Bruce C.
    Roberts, Mark E.
    ADVANCED MATERIALS, 2012, 24 (07) : 886 - +
  • [49] Effect of nanochitosan on electrochemical, interfacial and thermal properties of composite solid polymer electrolytes
    K. Karuppasamy
    S. Thanikaikarasan
    R. Antony
    S. Balakumar
    X. Sahaya Shajan
    Ionics, 2012, 18 : 737 - 745
  • [50] Electrical and electrochemical properties of magnesium ion conducting composite gel polymer electrolytes
    Pandey, G. P.
    Agrawal, R. C.
    Hashmi, S. A.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (25)