Transformations of para-substituted benzylcyclopropanes, allylbenzenes, and diphenylmethanes under nitration with nitric acid in acetic anhydride

被引：4
|
作者：
Mochalov, SS
Gazzaeva, RA
Fedotov, AN
Archegov, BP
Trofimova, EV
Shabarov, YS
Zefirov, NS
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119234, Russia
[2] Khetagurov N Osetian State Univ, N Osetia 362015, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 41卷 / 03期
关键词：
D O I：
10.1007/s11178-005-0179-x
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Electrophilic nitration of benzylcyclopropanes, allylbenzenes, and diphenylmethanes containing ortho,para-orienting substituents in the para position of the benzene ring results mainly in replacement of the cyclopropylmethyl, allyl, or benzyl group, respectively (ipso substitution). The nitration of 4-cyclopropylallyibenzene is not accompanied by nitrodealkylation, and the products are only 2- and 3-nitro-4-cyclopropylallylbenzenes.
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页码：406 / 416
页数：11
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