Porous TiO2/rGO nanocomposites prepared by cold sintering as efficient electrocatalyst for nitrogen reduction reaction under ambient conditions

Haber-Bosch process as the current dominant artificial NH3 production process in industry, requires relatively high temperature (350-550 degrees C) and pressure (150-350 atm). Electrocatalytic nitrogen reduction reaction (NRR) as a green and sustainable strategy for ammonia production has raised intensive research interest in recent years but still remains a significant challenge because of the lack of high performance electrocatalysts. In this work, porous TiO2-reduced graphene oxide (TiO2/rGO) nanocomposite as self-supporting efficient electrocatalyst for NRR under ambient conditions were prepared by cold sintering associated with sacrificial template method. The porous TiO2/rGO nanocomposite with grain size of similar to 40 nm were prepared by cold sintering process at 220 degrees C and 147 MPa. Given the 220 degrees C as cold sintering temperature, anatase TiO2 were preserved as the final phase which exhibit much better NRR electrocatalytic performance than the rutile phase. The oxygen vacancy densities in the nanocomposites were also tuned by heat treatment at 450 degrees C under different atmosphere, while samples heat treated under H-2/Ar atmosphere gave the best electrocatalytic NRR performance with a FE of 8.88 % and an NH3 yield of 7.75 mu g h(-1) cm(-2) at ambient conditions. Experiments also shows that the addition of rGO significantly improved the electrocatalytic NRR performance especially the conductivity. This work not only designed a framework of ceramic nanocomposites based self-supporting and durable electrocatalysts system but also paves a feasible way towards preparing electrocatalysts that are sensitive to high temperature fabrication process.