Determination of Abraham model solute descriptors for isophthalic acid from experimental solubility data in organic solvents at 298 K

被引：19

作者：

Schmidt, Amber ^{[1
]}

Grover, Damini ^{[1
]}

Zettl, Heidi ^{[1
]}

Koshevarova, Victoria ^{[1
]}

Dai, Colleen ^{[1
]}

Zhang, Shoshana ^{[1
]}

Hart, Erin ^{[1
]}

Brumfield, Michela ^{[1
]}

De La Rosa, Jennifer ^{[1
]}

Portillo, Valeria ^{[1
]}

Pugh, Ashley ^{[1
]}

Sanchez, Alfredo ^{[1
]}

Acree, William E., Jr. ^{[1
]}

Abraham, Michael H. ^{[2
]}

机构：

[1] Univ North Texas, Dept Chem, Denton, TX 76203 USA

[2] UCL, Dept Chem, London, England

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2016年 / 54卷 / 06期

基金：

美国国家科学基金会;

关键词：

Isophthalic acid solubilities; solubility predictions; alcohol solvents; Abraham model; solute descriptors; SOLVATION PARAMETER MODEL; MOBILE ORDER THEORY; CHEMICAL TOXICITY CORRELATIONS; HYDROGEN-BONDED SOLUTIONS; IDEAL BINARY SOLVENTS; GAS-PHASE; MATHEMATICAL CORRELATION; THERMOCHEMICAL INVESTIGATIONS; NONELECTROLYTE SOLVENTS; PREDICTED SOLUBILITIES;

D O I：

10.1080/00319104.2016.1149178

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental solubilities have been measured for isophthalic acid dissolved in eleven primary alcohol, three secondary alcohol and three alkoxyalcohol solvents at 298K. Results of the experimental measurements, combined with published solubility data for isophthalic acid in ethyl acetate, acetic acid, acetophenone, acetone, cyclohexanone, propyl acetate, N-methyl-2-pyrrolidone and tetrahydrofuran, were used to determine the Abraham model solute descriptors for isophthalic acid. The calculated solute descriptors described the measured solubility data to within an overall average standard deviation of 0.15 log units.

引用

页码：747 / 757

页数：11

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