Metal-polymer composites at liquid/liquid interfaces: new morphological investigations using ex situ and in situ studies

被引:4
|
作者
Divya, V. [1 ]
Sangaranarayanan, M. V. [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
Interfacial polymerization; Gold nanoparticles; Polymer composites; Specific conductivity; Fluorescence microscopy; Liquid/liquid Interface; LIQUID-LIQUID INTERFACE; POLYINDOLE-AU NANOCOMPOSITE; ELECTROCHEMICAL INSTABILITY; ELECTROCATALYTIC OXIDATION; NANOCRYSTALLINE FILMS; THIN-FILMS; NANOPARTICLES; GOLD; DEPOSITION; POLYCARBAZOLE;
D O I
10.1007/s10965-016-1050-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of gold-polyindole composites using water/dichloromethane interfaces is reported. It is demonstrated that the morphological features of the composites at the interface are not unique but depends upon the reactivity at various phases during the formation of the composite viz towards the aqueous and organic phases and as well as various locations of the interface. The morphological variations are analyzed using in situ Optical, Fluorescence and Laser Scanning and ex situ Scanning and Transmission Electron Microscopic techniques. The thermal stability of the composite is much higher than hitherto-known gold-polyindole composites, while this is the first report on the specific conductivity of any metal-polyindole composites.
引用
收藏
页码:1 / 10
页数:10
相关论文
共 50 条
  • [41] Size-controlled in situ synthesis of metal-polymer nanocomposite films using a CO2 laser
    Kashihara, Kazuhiko
    Uto, Yuki
    Nakajima, Takashi
    POLYMER BULLETIN, 2021, 78 (12) : 6969 - 6981
  • [42] An integrated in situ ATR-FTIR and EIS set-up to study buried metal-polymer interfaces exposed to an electrolyte solution
    Ohman, Maria
    Persson, Dan
    ELECTROCHIMICA ACTA, 2007, 52 (16) : 5159 - 5171
  • [43] In Situ Study of Buried Metal-Polymer Interfaces Exposed to an Aqueous Solution by an Integrated ATR-FTIR and Electrochemical Impedance Spectroscopy System
    Taheri, P.
    de Wit, J. H. W.
    Terryn, H.
    Mol, J. M. C.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (40): : 20826 - 20832
  • [44] In situ study of simultaneous adsorption of surfactant at model solid-liquid and liquid-liquid interfaces using the two-liquid contact angle method
    CNRS, Mulhouse, France
    J Adhes, 1-4 (191-202):
  • [45] In situ study of simultaneous adsorption of surfactant at model solid-liquid and liquid-liquid interfaces using the two-liquid contact angle method
    Haidara, H
    Noirot, S
    JOURNAL OF ADHESION, 1996, 57 (1-4): : 191 - 202
  • [46] Comparative performance of ex situ artificial solid electrolyte interphases for Li metal batteries with liquid electrolytes
    Lorandi, Francesca
    Liu, Tong
    Fantin, Marco
    Manser, Joe
    Al-Obeidi, Ahmed
    Zimmerman, Michael
    Matyjaszewski, Krzysztof
    Whitacre, Jay F.
    ISCIENCE, 2021, 24 (06)
  • [47] Nanoceramic-Metal Matrix Composites by In-Situ Pyrolysis of Organic Precursors in a Liquid Melt
    Sudarshan, M.
    Surappa, M. K.
    Ahn, Dongjoon
    Raj, Rishi
    METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2008, 39A (13): : 3291 - 3297
  • [48] In Situ Calorimetry at Metal-Electrode Liquid Electrolyte Interfaces As Monitored by Probe Beam Deflection Techniques
    Hai, Bin
    Scherson, Daniel
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42): : 18244 - 18250
  • [49] A new method of preparing in situ composites based on thermotropic liquid crystalline polymers and thermoplastics
    Yang, Gao-pin
    Ding, Yu-mei
    Yang, Wei-min
    AICAM 2005, 2006, 11-12 : 445 - +
  • [50] In situ TiB2/Cu composites fabricated by spray deposition using solid-liquid and liquid-liquid reactions
    Chen, Dan
    Jiang, Yi-hui
    Li, Yu-fa
    Liu, Di
    He, Jiang-tan
    Cao, Fei
    Liang, Shu-hua
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2020, 30 (07) : 1849 - 1856