Inverse microemulsion polymerization of acrylamide in the presence of N,N-dimethylacrylamide

被引：0

作者：

Juranicova, V

Kawamoto, S

Fujimoto, K

Kawaguchi, H

Barton, J ^{[1
]}

机构：

[1] Slovak Acad Sci, Inst Polymer, Inst Polymerizat React, Bratislava 84236, Slovakia

[2] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Yokohama, Kanagawa 223, Japan

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1998年 / 258卷

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The presence of N,N-dimethylacrylamide (NDA) influences the stability of initial, clear, single-phase Winsor IV inverse microemulsion composed of toluene/AOT (sodium salt of bis(2-ethylhexyl) sulfosuccinate)/NDA/water/acrylamide (AAm). For a molar fraction of NDA, n(NDA) = [NDA]/([NDA] + [AAm]) = 0.200 a single-phase system turned to a milky one during polymerization initiated by oil-soluble dibenzoyl peroxide or water-soluble ammonium peroxodisulfate, and finally a two-phase system was formed. For nNDA values greater than 0.200 also the precipitation of a polymeric product was observed during polymerization. The (co)polymerization rate of AAm and NDA exponentially decreases with increasing value of nNDA, while the reverse is true for the (co)polymer particle diameter. The results support the idea of simultaneously proceeding free-radical polymerization initiated by free radicals in continuous oil and dispersed water phase of the inverse microemulsion system.

引用

页码：27 / 31

页数：5

共 50 条

[31] Group transfer polymerization of N,N-dimethylacrylamide promoted by super Bronsted acid as an organocatalyst
Fuchise, Keita
Narumi, Atsushi
Sakai, Ryosuke
Satoh, Toshifumi
Kawaguchi, Seigou
Kakuchi, Toyoji
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[32] Copolymerization of N,N-dimethylacrylamide with n-butyl acrylate via atom transfer radical polymerization
Neugebauer, D
Matyjaszewski, K
MACROMOLECULES, 2003, 36 (08) : 2598 - 2603
[33] Cephazoline sodium release from poly(N-isopropyl acrylamide-co-N,N-dimethylacrylamide) hydrogels
Katime, I. (qfpkaarmi@lg.ehu.es), 1600, John Wiley and Sons Inc. (91):
[34] Polymerization of acrylamide in inverse microemulsion in the presence of mixtures of oleophilic and hydrophilic surfactants
Barton, J
Stillhammerova, M
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1996, 237 (237): : 113 - 122
[35] Synthesis of Poly(N,N-dimethylacrylamide)/Silica Gel Polymer Hybrids by in situ Polymerization Method
Ryo Tamaki
Kensuke Naka
Yoshiki Chujo
Polymer Journal, 1998, 30 : 60 - 65
[36] A tough and piezoelectric poly(acrylamide/N,N-dimethylacrylamide) hydrogel-based flexible wearable sensor
Wu, Mingyue
Wang, Guohui
Zhang, Mihan
Li, Jinchao
Wang, Chenglong
Sun, Guangdong
Zheng, Jinhuan
SOFT MATTER, 2024, 20 (34) : 6800 - 6807
[37] Polymerization of 4-vinylpyridine and N,N-dimethylacrylamide using a system without organic initiator
Xia, Sijing
Yang, Bin
Li, Guangzhao
Zhu, Xiaoqing
Wang, Anning
Zhu, Jin
POLYMER CHEMISTRY, 2011, 2 (10) : 2356 - 2359
[38] Cryopolymerization of N,N-dimethylacrylamide in moderately frozen formamide
O. E. Zaborina
M. I. Buzin
V. I. Lozinsky
Polymer Science Series B, 2012, 54 : 306 - 313
[39] Synthesis of poly(N,N-dimethylacrylamide) silica gel polymer hybrids by in situ polymerization method
Tamaki, R
Naka, K
Chujo, Y
POLYMER JOURNAL, 1998, 30 (01) : 60 - 65
[40] Polymerization of N,N-dimethylacrylamide in Aerosol OT-water mixtures:: from lamellae to segregation
Pacios, IE
Renamayor, CS
Horta, A
Lindman, B
Thuresson, K
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 218 (1-3) : 11 - 20

← 1 2 3 4 5 →