Synthesis and properties of chiral 1,8-disubstituted twistanes

被引:0
|
作者
Barnik, MI
Geivandov, RC
Gorina, II
Shtykov, NM
机构
[1] Russian State Sci Organ Intermediates & Dyes Inst, Moscow 13787, Russia
[2] Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia
关键词
liquid crystal; optical activity; spontaneous polarization; twistane;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Esters and alkyltwistanecyanbenzenes of the tricycle (4.4.0.0(3,8)) decane (twislane) have been prepared and their mesomorphic properties were examined. All the compounds are optically active and some esters have a chiral mesophase. Possibility was investigated of the application of twistane esters to induce ferroelectricity in the tilted smectic C phase of pyrimidines. The twistanes induce weak spontaneous polarization, and the reason for this effect is discussed.
引用
收藏
页码:251 / 259
页数:9
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