Convenient synthesis of functionalized 4,4′-disubstituted-2,2′-bipyridine with extended π-system for dye-sensitized solar cell applications

被引：17
|
作者：
Klein, Cedric [1 ]
Baranoff, Etienne [1 ]
Nazeeruddin, Md. Khaja [1 ]
Graetzel, Michael [1 ]
机构：
[1] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 47期
关键词：
Bipyridine; Horner-Emmons-Wadsworth reaction; Dye-sensitized solar cells; Extended pi-systems; RUTHENIUM COMPLEXES; BIPYRIDINE; EFFICIENT; ABSORPTIVITY; CHROMOPHORES;
D O I：
10.1016/j.tetlet.2010.09.077
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Exploration of new ruthenium-based sensitizers for dye-sensitized solar cell (DSC) applications requires an easy access to multifunctionalized ligands for efficient screening of sensitizers' properties. Based on the Horner-Emmons-Wadsworth reaction, a convenient synthetic route for the extension of the it-system on 4,4'-disubstituted-2,2'-bipyridines was used to develop a novel series of functionalized 2,2'-bipyridine ligands with either electron-withdrawing or donating end-capping group. H-1 NMR spectroscopy revealed that all the new bipyridyl ligands were obtained exclusively in their fully E isomers. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6161 / 6165
页数：5
相关论文
共 50 条
  • [41] Synthesis and Deposition of Rutile TiO2 for Dye-Sensitized Solar Cell Applications
    Teferi, Blen
    Schnupf, Udo
    Manseki, Kazuhiro
    Sugiura, Takashi
    Vafaei, Saeid
    PROCEEDINGS OF THE ASME INTERNATIONAL MECHANICAL ENGINEERING CONGRESS AND EXPOSITION, 2019, VOL 6, 2019,
  • [42] Synthesis and Characterization of 5′-Hexyl-2,2′-bithiophene Based on Organic Dyes for Dye-Sensitized Solar Cell Applications
    Saravanan, Chinnusamy
    Cho, Woosum
    Kim, Yulhee
    Jin, Sung-Ho
    Gal, Yeong-Soon
    Lee, Jae Wook
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2014, 599 (01) : 157 - 162
  • [43] Functionalized organic dyes containing a phenanthroimidazole donor for dye-sensitized solar cell applications
    Lee, Woochul
    Yang, Youna
    Cho, Nara
    Ko, Jaejung
    Hong, Jong-In
    TETRAHEDRON, 2012, 68 (27-28) : 5590 - 5598
  • [44] Functionalized alkyne bridged dendron based chromophores for dye-sensitized solar cell applications
    Baek, Nam Seob
    Yum, Jun-Ho
    Zhang, Xianxi
    Kim, Hwan Kyu
    Nazeeruddin, Mohammad K.
    Graetzel, Michael
    ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (10) : 1082 - 1087
  • [45] Tris(4,4′-di-t-butyl-2,2′-bipyridine)cobalt: Cation Effects on the Voltammetry at ITO and on Mediator Performance in Dye Sensitized Solar Cells
    Xue, Di
    Ashbrook, Lance N.
    Gaddie, Ross S.
    Elliott, C. Michael
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (06) : H355 - H359
  • [46] 4,4′-Diaminodiphenylsulfone; an efficient co-additive in dye-sensitized nanocrystalline TiO2 solar cells
    Afrooz, Malihe
    Bagheri, Omid
    Dehghani, Hossein
    APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (01)
  • [47] cis-Dichloro-bis(4,4'-dicarboxy-2,2-bipyridine)osmium(II)-modified optically transparent electrodes:: Application as cathodes in stacked dye-sensitized solar cells
    Scott, Michael J.
    Nelson, Jeremy J.
    Caramori, Stefano
    Bignozzi, Carlo A.
    Elliott, C. Michael
    INORGANIC CHEMISTRY, 2007, 46 (24) : 10071 - 10078
  • [48] Synthesis of 4,4′-dimethyl-2,2′-bipyridine catalyzed by Pd/C
    Wu, XH
    Yang, ZC
    Qin, W
    Jiang, ZH
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2006, 26 (02) : 260 - 262
  • [49] Synthesis of phthalocyanines with donor–acceptor properties and their applications to dye-sensitized solar cell
    B. Karadoğan
    F. Aytan Kılıçarslan
    I. Erden
    Chemical Papers, 2019, 73 : 2283 - 2288
  • [50] Synthesis, characterization and crystal structure of 6-Chloro-4,4′-dimethyl-2,2′-bipyridine and 4,4′-Dimethyl 2,2′-bipyridine N-Oxide
    Conterosito, Eleonora
    Magistris, Claudio
    Barolo, Claudia
    Croce, Gianluca
    Milanesio, Marco
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1107 : 337 - 343
12345