Demetallation of organometallic and metal-mediated reactions

被引：1
|
作者：
Li, Chao-Jun [1 ,2 ]
机构：
[1] McGill Univ, Dept Chem, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada
[2] McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada
来源：
INNOVATION | 2022年 / 3卷 / 04期
基金：
加拿大自然科学与工程研究理事会;
关键词：
C–C bond formations; C–H functionalization; organometallic reactions; sustainable chemical synthesis; umpolung hydrazones;
D O I：
10.1016/j.xinn.2022.100262
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The use of stoichiometric organometallic reagents and stoichiometric metals formed the basis of vast majority of classical reactions for constructing carbon-carbon bonds. The indispensable requirement of stoichiometric metals for such reactions constitutes significant challenges in terms of resource sustainability, operational safety, and chemical-waste management. The recent developments in C-H functionalizations, hydrogenative alkene/alkyne addition to electrophiles, the hydrazone umpolung chemistry, and other emerging fields such as the electrosynthesis and photoredox chemistry provide potential solutions to overcome these inherent challenges.
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页数：3
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