Influence of halide ions on the structure and properties of copper indium sulphide quantum dots

被引:8
|
作者
Marin, Riccardo [1 ,2 ]
Skripka, Artiom [2 ]
Huang, Yu-Cheng [3 ]
Loh, Tamie A. J. [3 ]
Mazeika, Viktoras [5 ]
Karabanovas, Vitalijus [5 ,6 ]
Chua, Daniel H. C. [4 ]
Dong, Chung-Li [3 ]
Canton, Patrizia [1 ]
Vetrone, Fiorenzo [2 ]
机构
[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, Via Torino 155-B, I-30170 Venice, Italy
[2] Univ Quebec, Inst Natl Rech Sci, Ctr Energie Mat & Telecommun INRS EMT, 1650 Boul Lionel Boulet, Varennes, PQ J3X 1S2, Canada
[3] Tamkang Univ, Dept Phys, Tamsui 25137, Taiwan
[4] Natl Univ Singapore, Dept Mat Sci & Engn, 9 Engn Dr 1, Singapore 117575, Singapore
[5] Natl Canc Inst, Biomed Phys Lab, P Baublio St 3b, LT-08406 Vilnius, Lithuania
[6] Vilnius Gediminas Tech Univ, Dept Chem & Bioengn, Sauletekio Ave 11, LT-10223 Vilnius, Lithuania
基金
加拿大自然科学与工程研究理事会;
关键词
OPTICAL-PROPERTIES; ELECTRONIC-STRUCTURE; NANOCRYSTALS; EFFICIENCY; EMISSION; DYNAMICS;
D O I
10.1039/c9cc08291c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the synthesis of CuInS2 quantum dots (QDs), the halide ions present in the copper salts influence the QD growth and optical properties. X-ray absorption spectroscopy allowed rationalizing the halide incorporation in the lattice and the dependence of electronic properties of the material on the ion's polarizability and interaction with hydrophobic moieties.
引用
收藏
页码:3341 / 3344
页数:4
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