The Mechanisms of Epoxy Latex Coatings Curing at Ambient Temperature Comparison with Solvent-type Ones

被引:0
|
作者
Guo, Qingquan [1 ]
Li, Daguang [1 ]
Guo, Jianwei [1 ]
Chen, Huanqin [2 ]
机构
[1] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou Univ City 510006, Peoples R China
[2] South China Univ Technol, Sch Chem & Energy Engn, Guangzhou 510640, Peoples R China
来源
ADVANCES IN COMPOSITES, PTS 1 AND 2 | 2011年 / 150-151卷
关键词
Epoxy Latex; Solvent-Type Epoxy Coating; Curing; Potlife; Infrared Spectrum;
D O I
10.4028/www.scientific.net/AMR.150-151.1249
中图分类号
TB33 [复合材料];
学科分类号
摘要
The performance and behavior of epoxy latex coatings are different from solvent-type ones. It is decided by the distinct curing mechanism. The solvent-type epoxy film obtained from epoxy resin and curing agent by homogeneous reaction, namely, the state of epoxy resin and curing agent is uniform. However, epoxy latex film made from epoxy resin emulsion or dispersion and water soluble amine by polyphase reaction. So the determination of potlife of epoxy latex can be showed by film gloss changes with residence time, dissimilar with solvent-type by the index of viscosity. The modern infrared spectrum measure shows that the epoxy groups in the dried epoxy latex film exist even if EEW to HAV proportion is 1.2:1. This also testifies the incomplete polyphase reaction mechanism of epoxy emulsion coating curing at ambient temperature.
引用
收藏
页码:1249 / +
页数:2
相关论文
共 43 条
  • [31] Fracture and toughening mechanisms of silica- and core-shell rubber-toughened epoxy at ambient and low temperature
    Tsang, Wing Lam
    Taylor, Ambrose C.
    JOURNAL OF MATERIALS SCIENCE, 2019, 54 (22) : 13938 - 13958
  • [32] Protective Mechanisms of Siloxane-Modified Epoxy Novolac Coatings at High-Pressure, High-Temperature Conditions
    Rajagopalan, Narayanan
    Olsen, Mads
    Larsen, Toke Skaarup
    Fjaelberg, Tine Jensen
    Weinell, Claus Erik
    Kiil, Soren
    ACS OMEGA, 2024, 9 (28): : 30675 - 30684
  • [33] Low-temperature-curing type positive-tone photosensitive polyimide coatings for insulating layer in OLED displays
    Okuda, R
    Miyoshi, K
    Arai, N
    Tomikawa, M
    Ohbayashi, G
    JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2002, 15 (02) : 205 - 208
  • [34] Solvent-free synthesis of phosphate-containing imidazole fluid for flame retardant one-component epoxy resin with long pot life, low curing temperature and fast curing rate
    Wang, Wei
    Chen, Gang
    Wu, Shulong
    Liu, Yuan
    Wang, Qi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (08)
  • [35] Influence of substrate metal alloy type on the properties of hydroxyapatite coatings deposited using a novel ambient temperature deposition technique
    Barry, J. N.
    Cowley, A.
    McNally, P. J.
    Dowling, D. P.
    JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2014, 102 (03) : 871 - 879
  • [36] AGING AND PERFORMANCE OF STRUCTURAL FILM ADHESIVES .1. A COMPARISON OF 2 HIGH-TEMPERATURE CURING, EPOXY-BASED SYSTEMS
    PEARCE, PJ
    DAVIDSON, RG
    MORRIS, CEM
    JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (11) : 4501 - 4516
  • [37] Temperature-dependent transport mechanisms through PE-CVD coatings: comparison of oxygen and water vapour
    Kirchheim, D.
    Wilski, S.
    Jaritz, M.
    Mitschker, F.
    Gebhard, M.
    Brochhagen, M.
    Boeke, M.
    Benedikt, Jan
    Awakowicz, P.
    Devi, A.
    Hopmann, Ch
    Dahlmann, R.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2017, 50 (39)
  • [38] Rational design of a room-temperature curing method, based on the epoxy-thiol click reaction, for UV-curable hard coatings with ultrahigh strength and adhesion
    Tanaka, Yuya
    Tanaka, Nanae
    Aoki, Daisuke
    Arimitsu, Koji
    JOURNAL OF POLYMER SCIENCE, 2024, : 5497 - 5506
  • [39] Solvent-free polyurethane coatings based on an in-situ curing strategy at room temperature with self-cleaning, anti-corrosion and anti-graffiti properties
    Luo, Haihang
    Wei, Huan
    Li, Heng
    Yao, Aisong
    Chen, Yi
    Zhao, Jianming
    Fan, Haojun
    PROGRESS IN ORGANIC COATINGS, 2024, 188
  • [40] COMPARISON OF ELEVATED-TEMPERATURE STRENGTH LOSS IN HIGH-TENSILE STRENGTH GRAPHITE-EPOXY COMPOSITE LAMINATES DUE TO AMBIENT AND ACCELERATED AGING
    HOFER, KE
    STANDER, M
    RAO, PN
    JOURNAL OF TESTING AND EVALUATION, 1975, 3 (06) : 423 - 426