Designer ligands: The search for metal ion selectivity

被引：6
|
作者：
Kaye, Perry T. [1 ]
机构：
[1] Rhodes Univ, Dept Chem, ZA-6140 Grahamstown, South Africa
来源：
SOUTH AFRICAN JOURNAL OF SCIENCE | 2011年 / 107卷 / 3-4期
基金：
新加坡国家研究基金会;
关键词：
CATALYTIC-ACTIVITY; ZN(II) COMPLEXES; COPPER; MN(II); NI(II);
D O I：
10.4102/sajs.v107i3/4.439
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
引用
收藏
页码：23 / 30
页数：8
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