Chromium(VI)-catalyzed oxidations by hydrogen peroxide: Influence of the presence of water and base

被引：0
|
作者：
Bouquillon, S [1 ]
Ait-Mohand, S [1 ]
Muzart, J [1 ]
机构：
[1] Univ Reims, CNRS, UMR React Select & Applicat, F-51687 Reims 2, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 1998卷 / 11期
关键词：
alcohols; chromium; oxidations; sodium percarbonate; peroxides;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chromium(VI)-catalyzed oxidation of 1-indanol into 1-indanone has bee carried out with sodium percarbonate (SPC), urea-hydrogen peroxide adduct (UHP), or aqueous hydrogen peroxide. It has been established that the superiority of SPC over UHP and aqueous H2O2 is due both to its nonhydrated structure and its basic properties. This classifies SPC as a "dry basic carrier of H2O2".
引用
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页码：2599 / 2602
页数：4
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