Wacker oxidation of alkenes using a fluorous biphasic system. A mild preparation of polyfunctional ketones

被引：61
|
作者：
Betzemeier, B [1 ]
Lhermitte, F [1 ]
Knochel, P [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 37期
关键词：
D O I：
10.1016/S0040-4039(98)01355-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various alkenes are oxidized to the corresponding ketones using t-BuOOH in the presence of a palladium(II) catalyst bearing perfluorinated ligands using a biphasic solvent system of benzene and bromoperfluorooctane. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6667 / 6670
页数：4
相关论文
共 50 条
  • [11] Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System
    Zeng, Tian
    Liu, Zhen
    Schmidt, Michael A.
    Eastgate, Martin D.
    Engle, Keary M.
    ORGANIC LETTERS, 2018, 20 (13) : 3853 - 3857
  • [12] Selective Wacker-type oxidation of terminal alkenes and dienes using the Pd(II)/molybdovanadophosphate (NPMoV)/O2 system
    Yokota, T
    Sakakura, A
    Tani, M
    Sakaguchi, S
    Ishii, Y
    TETRAHEDRON LETTERS, 2002, 43 (49) : 8887 - 8891
  • [13] Catalytic Methods for Producing Higher 2-Ketones: Prospects for the Wacker System in the Oxidation of α-Olefins (A Review)
    Yu. A. Rodikova
    E. G. Zhizhina
    Kinetics and Catalysis, 2023, 64 : 105 - 121
  • [14] PREPARATION OF ALPHA-HYDROXY KETONES BY OXIDATION OF ALKENES WITH POTASSIUM-PERMANGANATE IN AQUEOUS ACETONE
    SRINIVASAN, NS
    LEE, DG
    SYNTHESIS-STUTTGART, 1979, (07): : 520 - 521
  • [15] DIRECT OXIDATION OF ALKENES TO KETONES USING PEROXYTRIFLUOROACETIC ACID-BORON FLUORIDE
    HART, H
    LERNER, LR
    JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (09): : 2669 - &
  • [16] Catalytic Methods for Producing Higher 2-Ketones: Prospects for the Wacker System in the Oxidation of a-Olefins (A Review)
    Rodikova, Yu. A.
    Zhizhina, E. G.
    KINETICS AND CATALYSIS, 2023, 64 (02) : 105 - 121
  • [17] A biphasic oxidation of alcohols to aldehydes and ketones using a simplified packed-bed microreactor
    Bogdan, Andrew
    McQuade, D. Tyler
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2009, 5
  • [18] Palladium(II)-catalyzed oxidation of terminal alkenes to methyl ketones using molecular oxygen
    Uemura, S., 1915, Royal Society of Chemistry
  • [19] Palladium(II)-catalyzed oxidation of terminal alkenes to methyl ketones using molecular oxygen
    Nishimura, T
    Kakiuchi, N
    Onoue, T
    Ohe, K
    Uemura, S
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (12): : 1915 - 1918
  • [20] Conversion of Olefins into Ketones by an Iron-Catalyzed Wacker-type Oxidation Using Oxygen as the Sole Oxidant
    Puls, Florian
    Knoelker, Hans-Joachim
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (05) : 1222 - 1226
12345