Recent Advances and Perspectives of Transition Metal-Catalyzed Asymmetric Fluorination Reactions

被引：38

作者：

Chen, Chaohuang ^{[1
]}

Fu, Liang ^{[1
]}

Chen, Pinhong ^{[1
]}

Liu, Guosheng ^{[1
]}

机构：

[1] Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2017年 / 35卷 / 12期

关键词：

metal-catalyzed; asymmetric; fluorination; trifluoromethylthiolation; trifluoromethoxylation; C-H FLUORINATION; ENANTIOSELECTIVE FLUORINATION; OXIDATIVE AMINOFLUORINATION; ELECTROPHILIC FLUORINATION; REDUCTIVE ELIMINATION; ALLYLIC FLUORINATION; BOND FORMATION; PALLADIUM; TRIFLUOROMETHYLATION; TRIFLUOROMETHOXYLATION;

D O I：

10.1002/cjoc.201700489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of fluorine-containing molecules has received intensive attention in recent years due to the great value of fluorides, however, the transition metal-catalyzed asymmetric construction of CF bonds is much less developed. This review presents the recent advancement of transition metal-catalyzed asymmetric fluorination reactions, in which the final CF bond is from reductive elimination of organometallic complexes. In addition, the perspective of the field is also provided for the future studies of asymmetric fluorinations and the related transformations, such as trifluoromethylation, trifluoromethylthiolation and trifluoromethoxylation.

引用

页码：1781 / 1788

页数：8

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