Chlorination of 5-nitro-6-methyluracil and its N(1),N(3)-dimethyl analogue with molecular chlorine

被引：4
|
作者：
Chernikova, Irma B. [1 ]
Khursan, Sergey L. [1 ]
Yunusov, Marat S. [1 ]
Yumagulov, Rustam A. [1 ,2 ]
机构：
[1] Russian Acad Sci, Ufa Inst Chem, Ufa 450054, Russia
[2] Bashkir State Univ, Ufa 450000, Russia
来源：
MENDELEEV COMMUNICATIONS | 2015年 / 25卷 / 03期
关键词：
D O I：
10.1016/j.mencom.2015.05.022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chlorination of 6-methyl-5-nitrouracil with chlorine in methanol results in a two-component mixture of 5-ehloro-6-methyl-6-methoxy-5-nitro-5,6-dihydrouracils, while the chlorination of 5-nitro-1,3,6-trimethyluracil under similar conditions gives a mixture of 5-chloro-6-hydroxy-5-nitro-1,3,6-trimethyl-5,6-dihydrouracils. The structures of the chlorination products were suggested based on quantum-chemical calculations.
引用
收藏
页码：221 / 223
页数：3
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