New synthetic routes to the kainoids: a synthesis of kainic acid and its analogues

被引：11

作者：

Parsons, Philip J. ^{[1
]}

Rushton, Stephen P. G. ^{[1
]}

Panta, Raghava R. ^{[1
]}

Murray, Adrian J. ^{[1
]}

Coles, Martyn P. ^{[1
]}

Lai, Jason ^{[1
]}

机构：

[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

TETRAHEDRON | 2011年 / 67卷 / 52期

关键词：

Excitatory amino acids; Nitrile oxide; Kainate; Ene-reaction; Isoxazolidinone; ENANTIOSELECTIVE TOTAL-SYNTHESIS; (-)-KAINIC ACID; (-)-ALPHA-KAINIC ACID; (+)-ALPHA-ALLOKAINIC ACID; CYCLIZATION; INSERTION;

D O I：

10.1016/j.tet.2011.10.030

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New approaches to the synthesis of kainic acid and its analogues are presented. Two distinctly different approaches are described; the former utilised an intermolecular nitrile oxide addition to a homochiral substrate to furnish epikainate models and the second utilised amino acid chemistry to secure kainic acid. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：10267 / 10273

页数：7

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