Aerobic, Cu-catalyzed desulfitative C-C bond-forming reaction of ketene dithioacetals/vinylogous thioesters and arylboronic acids

被引：44
|
作者：
Dong, Ying [1 ]
Wang, Mang [1 ,2 ]
Liu, Jun [1 ]
Ma, Wei [1 ]
Liu, Qun [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
[2] Nankai Univ, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 26期
关键词：
BORONIC ACIDS; TETRASUBSTITUTED OLEFINS; ORGANOBORON COMPOUNDS; COPPER; ESTERS; BENZOFURANS; TRI;
D O I：
10.1039/c1cc11382h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Cu-catalyzed thioorganic-boronic acid desulfitative C-C bond-forming reaction involving ketene dithioacetals/ vinylogous thioesters is reported to proceed without the assistance of ligating S-pendant. Vinylogous thiolesters and tetrasubstituted olefins were prepared by this reaction in which Cu catalyst plays a dual role under aerobic conditions.
引用
收藏
页码：7380 / 7382
页数：3
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